Volume 25
Main Index

Issue 01

Masthead DOI: 10.1021/ar00013a700

Editorial. Dedication of the Silver Anniversary Volume to Joseph F. Bunnett, Founding Editor Fred McLafferty pp 1–1 DOI: 10.1021/ar00013a600

Radical-chain, electron-transfer dehalogenation reactions Joseph F. Bunnett pp 2–9 DOI: 10.1021/ar00013a001

The principle of nonperfect synchronization: more than a qualitative concept? Claude F. Bernasconi pp 9–16 DOI: 10.1021/ar00013a002

Asymmetric reduction with chiral organoboranes based on .alpha.-pinene Herbert C. Brown, P. Veeraraghavan Ramachandran pp 16–24 DOI: 10.1021/ar00013a003

Chemistry on stamps (chemophilately) Zvi Rappoport pp 24–31 DOI: 10.1021/ar00013a004

Reactions of halodiazirines by SN2' and electron transfer initiated processes Xavier Creary pp 31–38 DOI: 10.1021/ar00013a005

Inner-sphere electron transfer in organic chemistry. Relevance to electrophilic aromatic nitration Jay K. Kochi pp 39–47 DOI: 10.1021/ar00013a006

Three-center, two-electron C-H-C bonds in organic chemistry John E. McMurry, Thomas Lectka pp 47–53 DOI: 10.1021/ar00013a007

Issue 02

Masthead DOI: 10.1021/ar00014a700

Surface-bound metal hydrocarbyls. Organometallic connections between heterogeneous and homogeneous catalysis Tobin J. Marks pp 57–65 DOI: 10.1021/ar00014a001

Molecular quantum beats. High-resolution spectroscopy in the time domain Herbert Bitto, J. Robert Huber pp 65–71 DOI: 10.1021/ar00014a002

Orbital stereochemistry: discovering the symmetries of collision processes Stephen R. Leone pp 71–76 DOI: 10.1021/ar00014a003

Oligosaccharins: oligosaccharide regulatory molecules Peter Albersheim, Alan Darvill, Christopher Augur, Jong Joo Cheong, Stefan Eberhard, Michael G. Hahn, Victoria Marfa, Debra Mohnen, Malcolm A. O'Neill, pp 77–83 DOI: 10.1021/ar00014a004

Development of organopalladium(IV) chemistry: fundamental aspects and systems for studies of mechanism in organometallic chemistry and catalysis Allan J. Canty pp 83–90 DOI: 10.1021/ar00014a005

Expanding the analogy between phosphorus-carbon and carbon-carbon double bonds Francois Mathey pp 90–96 DOI: 10.1021/ar00014a006

Issue 03

Masthead DOI: 10.1021/ar00015a700

Editorial Fred McLafferty pp 97–97 DOI: 10.1021/ar00014a600

Editorial Fred McLafferty pp 97–97 DOI: 10.1021/ar00015a600

Self-assembly of the fullerenes R. E. Smalley pp 98–105 DOI: 10.1021/ar00015a001

A postbuckminsterfullerene view of carbon in the galaxy J. P. Hare, H. W. Kroto pp 106–112 DOI: 10.1021/ar00015a002

Solid-state chemistry of fullerene-based materials John E. Fischer, Paul A. Heiney, Amos B. Smith III pp 112–118 DOI: 10.1021/ar00015a003

Beyond C60: the higher fullerenes Francois Diederich, Robert L. Whetten pp 119–126 DOI: 10.1021/ar00015a004

Electronic structure, conductivity and superconductivity of alkali metal doped (C60) R. C. Haddon pp 127–133 DOI: 10.1021/ar00015a005

Metal complexes of buckminsterfullerene (C60) Paul J. Fagan, Joseph C. Calabrese, Brian Malone pp 134–142 DOI: 10.1021/ar00015a006

Fullerenes and fullerides: photoemission and scanning tunneling microscopy studies John H. Weaver pp 143–149 DOI: 10.1021/ar00015a007

Osmylation of C60: proof and characterization of the soccer-ball framework Joel M. Hawkins pp 150–156 DOI: 10.1021/ar00015a008

The chemical properties of buckminsterfullerene (C60) and the birth and infancy of fulleroids Fred Wudl pp 157–161 DOI: 10.1021/ar00015a009

Characterization of fullerenes by mass spectrometry Stephen W. McElvany, Mark M. Ross, John H. Callahan pp 162–168 DOI: 10.1021/ar00015a010

Fullerene structure and dynamics: a magnetic resonance potpourri Robert D. Johnson, Donald S. Bethune, Costantino S. Yannoni pp 169–175 DOI: 10.1021/ar00015a011

Issue 04

Masthead DOI: 10.1021/ar00016a700

Protonation of coordinated dinitrogen G. J. Leigh pp 177–181 DOI: 10.1021/ar00016a001

Synthetic applications of organoantimony compounds Yaozeng Huang pp 182–187 DOI: 10.1021/ar00016a002

Organosilanes as radical-based reducing agents in synthesis Chryssostomos Chatgilialoglu pp 188–194 DOI: 10.1021/ar00016a003

Fluorescence resonance energy transfer on fractals T. Gregory Dewey pp 195–200 DOI: 10.1021/ar00016a004

The RNA-folding problem David E. Draper pp 201–207 DOI: 10.1021/ar00016a005

Issue 05

Masthead DOI: 10.1021/ar00017a700

New angles in nuclear magnetic resonance sample spinning E. Wrenn Wooten, Karl T. Mueller, Alexander Pines pp 209–215 DOI: 10.1021/ar00017a001

Determinations of transition-state geometries by the endocyclic restriction test: mechanisms of substitution at nonstereogenic atoms Peter Beak pp 215–222 DOI: 10.1021/ar00017a002

Chemistry of organochromium(III) complexes James H. Espenson pp 222–227 DOI: 10.1021/ar00017a003

The transient grating: a holographic window to dynamic processes John T. Fourkas, M. D. Fayer pp 227–233 DOI: 10.1021/ar00017a004

Mechanistic and synthetic aspects of amine-enone single electron transfer photochemistry Ung Chan Yoon, Patrick S. Mariano pp 233–240 DOI: 10.1021/ar00017a005

Issue 06

Masthead DOI: 10.1021/ar00018a700

Discoveries concerning the transport of colloids and new forms of chromatography Hamish Small pp 241–246 DOI: 10.1021/ar00018a001

Mathematical inorganic chemistry: from gas-phase metal clusters to superconducting solids R. Bruce King pp 247–253 DOI: 10.1021/ar00018a002

Dynamic Monte Carlo Simulations of Surface-Rate Processes H. Kang, W. Weinberg pp 253–259 DOI: 10.1021/ar00018a600

Preparation and reactivity of alkyl groups adsorbed on metal surfaces Francisco Zaera pp 260–265 DOI: 10.1021/ar00018a003

Heterogeneous, platinum-catalyzed hydrogenations of (diolefin)dialkylplatinum(II) complexes T. Randall Lee, George M. Whitesides pp 266–272 DOI: 10.1021/ar00018a004

Fusion reactions in dense hot atom assemblies generated by cluster impact. [Erratum to document cited in CA115(6):58473r] R. J. Beuhler, G. Friedlander, Lewis Friedman pp 272–272 DOI: 10.1021/ar00018a005

Issue 07

Masthead DOI: 10.1021/ar00019a700

Model studies of metalloenzymes involving metal ions as Lewis acid catalysts Junghun Suh pp 273–279 DOI: 10.1021/ar00019a001

On the molecular mechanisms of the solar to electric energy conversion by the other photosynthetic system in nature, bacteriorhodopsin M. A. El-Sayed pp 279–286 DOI: 10.1021/ar00019a002

Titan: a laboratory for prebiological organic chemistry Carl Sagan, W. Reid Thompson, Bishun N. Khare pp 286–292 DOI: 10.1021/ar00019a003

Energy flow from excited molecules on salt surfaces George E. Ewing pp 292–299 DOI: 10.1021/ar00019a004

Photochemical and photophysical studies of organic molecules included within zeolites V. Ramamurthy, D. F. Eaton, J. V. Caspar pp 299–307 DOI: 10.1021/ar00019a005

Nucleoside phosphate sugars: syntheses on practical scales for use as reagents in the enzymatic preparation of oligosaccharides and glycoconjugates Jurgen E. Heidlas, Kevin W. Williams, George M. Whitesides pp 307–314 DOI: 10.1021/ar00019a006

Mechanism of alkene epoxidation by iron, chromium, and manganese higher valent oxo-metalloporphyrins Drazen Ostovic, Thomas C. Bruice pp 314–320 DOI: 10.1021/ar00019a007

Issue 08

Masthead DOI: 10.1021/ar00020a700

The elusive equilibrium bond length in organic polyatomic molecules: finally obtainable from spectroscopy? Marlin D. Harmony pp 321–327 DOI: 10.1021/ar00020a001

Low-dimensional solids: an interface between molecular and solid-state chemistry? The example of chainlike niobium and tantalum chalcogenides J. Rouxel pp 328–336 DOI: 10.1021/ar00020a002

Polyelectrolyte-sensitized phospholipid vesicles James L. Thomas, David A. Tirrell pp 336–342 DOI: 10.1021/ar00020a003

The electronic structures of active sites in non-heme iron enzymes Edward I. Solomon, Yan Zhang pp 343–352 DOI: 10.1021/ar00020a004

Charge as a key component in reaction design. The invention of cationic cyclization reactions of importance in synthesis Larry E. Overman pp 352–359 DOI: 10.1021/ar00020a005

Stereoselective routes toward the synthesis of unusual amino acids Yasufumi Ohfune pp 360–366 DOI: 10.1021/ar00020a006

Prediction of high concentration band profiles in liquid chromatography Anita M. Katti, Moustapha Diack, M. Zoubair El Fallah, Sadroddin Golshan-Shirazi, Stephen C. Jacobson, Andreas Seidel-Morgenstern, Georges Guiochon pp 366–374 DOI: 10.1021/ar00020a007

The covalent potential: a simple and useful measure of the valence-state electronegativity for correlating molecular energetics Yu Ran Luo, Sidney W. Benson pp 375–381 DOI: 10.1021/ar00020a008

An analysis of the Benson-Luo approach and electronegativities in general Russell S. Drago pp 382–383 DOI: 10.1021/ar00020a009

Issue 09

Masthead DOI: 10.1021/ar00021a700

Photoionization mass and photoelectron spectroscopy of radicals, carbenes, and biradicals Joel A. Blush, Horst Clauberg, Daniel W. Kohn, David W. Minsek, Xu Zhang, Peter Chen pp 385–392 DOI: 10.1021/ar00021a001

Spider silk: the unraveling of a mystery Randolph V. Lewis pp 392–398 DOI: 10.1021/ar00021a002

Hopanoids. 1. Geohopanoids: the most abundant natural products on Earth? Guy Ourisson, Pierre Albrecht pp 398–402 DOI: 10.1021/ar00021a003

Hopanoids. 2. Biohopanoids: a novel class of bacterial lipids Guy Ourisson, Michel Rohmer pp 403–408 DOI: 10.1021/ar00021a004

Mapping the genesis of helical structure in polymers of the trihaloacetaldehydes Otto Vogl, Gary D. Jaycox, Christoph Kratky, William J. Simonsick Jr., Koichi Hatada pp 408–413 DOI: 10.1021/ar00021a005

Studies of interstellar ion reactions using the SIFT technique: isotope fractionation David Smith, Patrik Spanel pp 414–420 DOI: 10.1021/ar00021a006

Layered metal phosphates and phosphonates: from crystals to monolayers Guang Cao, Hun Gi Hong, Thomas E. Mallouk pp 420–427 DOI: 10.1021/ar00021a007

Vibrational spectroscopy of high-temperature, dense molecular fluids by coherent anti-Stokes Raman scattering Stephen C. Schmidt, David S. Moore pp 427–432 DOI: 10.1021/ar00021a008

Issue 10

Masthead DOI: 10.1021/ar00022a700

Isocyanides and cyanides as natural products Paul J. Scheuer pp 433–439 DOI: 10.1021/ar00022a001

Analytical chemistry in microenvironments: single nerve cells Andrew G. Ewing, Timothy G. Strein, Yau Yi Lau pp 440–447 DOI: 10.1021/ar00022a002

Is N,N,N',N'-tetramethylethylenediamine a good ligand for lithium? David B. Collum pp 448–454 DOI: 10.1021/ar00022a003

Do bond-stretch isomers really exist? Gerard Parkin pp 455–460 DOI: 10.1021/ar00022a004

Gas-phase carbanion chemistry Robert R. Squires pp 461–467 DOI: 10.1021/ar00022a005

D-Alanyl-D-alanine ligases and the molecular mechanism of vancomycin resistance Gerard D. Wright, Christopher T. Walsh pp 468–473 DOI: 10.1021/ar00022a006

The rapid steps in nucleophilic vinylic addition-elimination substitution. Recent developments Zvi Rappoport pp 474–479 DOI: 10.1021/ar00022a007

Issue 11

Masthead DOI: 10.1021/ar00023a700

Recent perspectives concerning the mechanism of H3O+- and hydroxide-promoted amide hydrolysis R. S. Brown, A. J. Bennet, H. Slebocka-Tilk pp 481–488 DOI: 10.1021/ar00023a001

Hot spot ignition mechanisms for explosives John E. Field pp 489–496 DOI: 10.1021/ar00023a002

Molecular design, chemical synthesis, and biological action of enediynes Kyriacos C. Nicolaou, Adrian L. Smith pp 497–503 DOI: 10.1021/ar00023a003

The selective functionalization of saturated hydrocarbons: Gif chemistry Derek H. R. Barton, Dario Doller pp 504–512 DOI: 10.1021/ar00023a004

Randomness and complexity in chemical physics Peter G. Wolynes pp 513–519 DOI: 10.1021/ar00023a005

Intramolecular dynamics for the organic chemist Barry K. Carpenter pp 520–528 DOI: 10.1021/ar00023a006

Carboranylhalonium ions: from striking reactivity to a unified mechanistic analysis of polar reactions of diarylhalonium compounds V. V. Grushin pp 529–536 DOI: 10.1021/ar00023a007

Mechanisms of pericyclic reactions: the role of quantitative theory in the study of reaction mechanisms Michael J. S. Dewar, Caoxian Jie pp 537–543 DOI: 10.1021/ar00023a008

Issue 12

Masthead DOI: 10.1021/ar00024a700

Probing the synthetic capabilities of a center of biochemical catalysis Sidney M. Hecht pp 545–552 DOI: 10.1021/ar00024a001

Smart zeolites: new forms of tungsten and molybdenum oxides Geoffrey A. Ozin, Saim Ozkar, Richard A. Prokopowicz pp 553–560 DOI: 10.1021/ar00024a002

Solitons in a box: the organic chemistry of electrically conducting polyenes Laren M. Tolbert pp 561–568 DOI: 10.1021/ar00024a003

Polymeric and supramolecular arrays for directional energy and electron transport over macroscopic distances Marye Anne Fox pp 569–574 DOI: 10.1021/ar00024a004

Saccharides of biological importance: challenges and opportunities for organic synthesis Per J. Garegg pp 575–580 DOI: 10.1021/ar00024a005

Mechanisms of metal atom formation in the multiphoton dissociation of organometallic molecules Robert L. Jackson pp 581–586 DOI: 10.1021/ar00024a006